Protein Concentration Calculator

A280 Protein Concentration Calculator

Calculate protein concentration from UV absorbance at 280nm using the Beer-Lambert law. Includes A260/A280 purity assessment for nucleic acid contamination.

Last updated: March 2026

Beer-Lambert Law Calculator

For purity check
(mg/mL)⁻¹ cm⁻¹
cm (cuvette width)
1 = undiluted
kDa (for µM calculation)

What is Protein Concentration Measurement?

Protein concentration measurement is fundamental in biochemistry and molecular biology. Accurate quantification is essential for enzyme activity assays, SDS-PAGE loading, Western blotting, protein purification monitoring and standardizing experimental conditions.

The Beer-Lambert law describes the relationship between absorbance, concentration and optical path length: A = ε × c × l. At 280 nm, proteins absorb ultraviolet light primarily because of tryptophan and tyrosine residues, with a smaller contribution from cystine.

This calculator uses a mass extinction coefficient in (mg/mL)⁻¹ cm⁻¹, allowing protein concentration to be calculated directly in mg/mL. Do not enter a molar extinction coefficient expressed in M⁻¹ cm⁻¹.

Common protein quantification methods include direct A280 measurement, the Bradford assay and the BCA assay. A280 is fast and non-destructive, while Bradford and BCA assays use calibration curves prepared from known protein standards.

How to Measure Protein Concentration

Beer-Lambert Law

A = ε × c × l
• A = Absorbance at 280 nm
• ε = Mass extinction coefficient in (mg/mL)⁻¹ cm⁻¹
• c = Protein concentration in mg/mL
• l = Optical path length in cm
c = (A / (ε × l)) × Dilution Factor

This calculator requires a mass extinction coefficient. A molar extinction coefficient in M⁻¹ cm⁻¹ cannot be entered directly without conversion.

Common Methods

A280 UV Absorbance
• Wavelength: 280 nm
• Measures absorbance associated mainly with tryptophan and tyrosine residues
• Pros: Fast, non-destructive and requires no reagent
• Cons: Requires a relatively pure sample and a known mass extinction coefficient
Bradford Assay
• Wavelength: 595 nm
• Based on binding of Coomassie Brilliant Blue G-250 dye
• Pros: Fast, sensitive and widely used
• Cons: Results depend on the protein standard and some detergents can interfere
• Concentration is determined from a calibration curve
BCA Assay
• Wavelength: 562 nm
• Based on copper reduction followed by formation of a purple BCA complex
• Pros: Broad working range and good detergent compatibility
• Cons: Some reducing agents and chelating compounds can interfere
• Concentration is determined from a calibration curve

When is A280 Appropriate?

A280 measurement is most appropriate for purified or partially purified protein samples when a suitable mass extinction coefficient is available.

  • Measure a matching buffer blank before measuring the protein sample.
  • Use the optical path length reported by the instrument or cuvette.
  • Apply the correct dilution factor when the sample has been diluted.
  • Check that absorbance falls within the validated linear range of the instrument.
  • Consider Bradford or BCA assays when contaminants interfere with UV absorbance.

Worked Example

Calculate BSA protein concentration:

Given:
• Absorbance at 280nm: 0.543
• Extinction coefficient (BSA): 1.0 (mg/mL)⁻¹ cm⁻¹
• Path length: 1 cm (standard cuvette)
• Dilution factor: 10 (sample was diluted 1:10)
Step 1:
Apply Beer-Lambert law:
c = A / (ε × l)
c = 0.543 / (1.0 × 1)
c = 0.543 mg/mL
This is the concentration in the measured (diluted) sample
Step 2:
Account for dilution:
coriginal = cmeasured × Dilution Factor
coriginal = 0.543 × 10
coriginal = 5.43 mg/mL
Result:
5.43 mg/mL
The original protein sample concentration is 5.43 mg/mL or 5,430 µg/mL

Further Reading

For more information about protein quantification, UV absorbance and extinction coefficients, see these authoritative resources:

Frequently Asked Questions

How do I find extinction coefficient?

For purified proteins, calculate from sequence using ProtParam (ExPASy) which counts Trp, Tyr, and Cys residues. Typical values: BSA = 0.7, IgG = 1.4, lysozyme = 2.6 (all in (mg/mL)⁻¹ cm⁻¹ at 280nm). For unknown proteins, use Bradford or BCA with BSA standard.

Why dilute samples?

Spectrophotometers are accurate in absorbance range 0.1-1.0. Outside this range, measurements become nonlinear. If A > 1.0, dilute the sample. The dilution factor corrects back to original concentration. Most assays have optimal absorbance ranges for best accuracy.

What interferes with measurements?

A280: nucleic acids (absorb at 280nm), turbidity, reducing agents. Bradford: detergents (SDS, Triton), high salt, basic pH. BCA: reducing agents (DTT, β-ME), chelators (EDTA), lipids. Always include appropriate blanks with your buffer.

Which method should I use?

A280 for pure proteins (fastest, no reagents). Bradford for crude lysates (compatible with reducers). BCA for samples with detergents or when higher sensitivity needed. For unknown proteins, use Bradford or BCA with BSA standard curve.

What is a standard curve?

For Bradford/BCA, prepare known BSA concentrations (0-2 mg/mL), measure absorbance, plot A vs concentration, fit a line/curve. Unknown protein absorbance is compared to this curve to determine concentration. Curves are method and plate-reader specific.

Why use BSA as standard?

Bovine serum albumin (BSA) is cheap, pure, stable, and well-characterized. It's the universal protein standard. However, different proteins bind Bradford/BCA reagents differently, so BSA curves give approximate concentrations. For precision, use a purified version of your target protein as standard.

Can I use different path lengths?

Yes. Microvolume (1mm path) uses only 1-2 µL sample. Standard cuvettes are 1 cm path. Formula still applies: shorter path = lower absorbance, so scale accordingly. Most spectrophotometers have cuvette adapters or built-in microvolume pedestal (e.g., NanoDrop).

How accurate are these methods?

A280: ±5% with known ε and pure protein. Bradford: ±10-15% due to protein-to-protein variation in dye binding. BCA: ±5-10%, more consistent across proteins. Always measure in triplicate and use freshly prepared standards for best accuracy.

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